Skip to main content
SpringerLink
Log in

Vapor—Liquid equilibrium for binary mixtures of isomericaln-octenes with some solvents

Dampf-flüssig Gleichgewicht für binäre Mischungen von isomeren n-Octenen mit einigen Lösungsmitteln

  • Inorganic and Physical Chemistry
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Measurements of isobaric temperature—liquid composition are reported in the binary systems formed from 1-octene,cis-4-octene andtrans-4-octene with methyl cellosolve (2-methoxyethanol), 1-butanol and tetrachloroethene at pressures of 760 and 200 mm Hg (101.325 and 26.664 kPa). These systems have minimum boiling azeotropes. TheWilson equation is used to predict the liquid phase activity coefficients. The γ i −χ i functions thus obtained are compared in the systems containing a solvent common to the three isomericn-octenes.

Zusammenfassung

Es werden thermodynamische Daten (isobare Siedetemperatur—Zusammensetzung der flüssigen Phase) und die Azeotrope der binären Systeme aus 1-Octen,cis-4-Octen undtrans-4-Octen mit Methylcellosolv (2-Methoxyethanol), 1-Butanol und Tetrachlorethen bei Drücken von 760 mm Hg (101,325 kPa) und 200 mm Hg (26,664 kPa) angegeben. DieWilsongleichung wurde zur Vorhersage der Aktivitätskoeffizienten in flüssiger Phase eingesetzt. Die so erhaltenen415-2 Funktionen werden für Mischungen der drei isomerenn-Octene mit jeweils einem gemeinsamen Lösungsmittel verglichen.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Kuus, M., Kudryavtseva, L., Eisen, O., Eesti NSV Tead. Akad. Toim., Keem.29, 25 (1980).

    Google Scholar 

  2. Kuus, M., Toome, M., Kudryavtseva, L., Eisen, O., Eesti NSV Tead. Akad. Toim., Keem.29, 32 (1980).

    Google Scholar 

  3. Woycicki, W., J. Chem. Thermodyn.7, 77 (1975).

    Google Scholar 

  4. Woycicki, W., J. Chem. Thermodyn.7, 1007 (1975).

    Google Scholar 

  5. Kudryavtseva, L., Viit, H., Eisen, O., Eesti NSV Tead. Akad. Toim., Keem. Geol.18, 346 (1969).

    Google Scholar 

  6. Kudryavtseva, L., Viit, H., Eisen, O., Eesti NSV Tead. Akad. Toim., Keem. Geol.19, 22 (1970).

    Google Scholar 

  7. Suryanarayana, Y. S., van Winkle, M., J. Chem. Eng. Data11, 7 (1966).

    Google Scholar 

  8. Hanson, D. O., van Winkle, M., J. Chem. Eng. Data12, 319 (1967).

    Google Scholar 

  9. Tassios, D., van Winkle, M., J. Chem. Eng. Data12, 555 (1967).

    Google Scholar 

  10. Mihkelson, V., Kirss, H., Kudryavtseva, L., Eisen, O., Fluid Phase Equilibria, 201 (1977/1978).

  11. Henne, A. L., Greenlee, K. W., J. Amer. Chem. Soc.10, 2020 (1943).

    Google Scholar 

  12. Brown, C. A., Ahuja, V. K., J. Org. Chem.38, 2226 (1973).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Estonian Academy of Sciences, Tallinn, USSR

    Mati Kuus, L. Kudryavtseva, H. Kirss & O. Eisen

Authors
  1. Mati Kuus
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. Kudryavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Kirss
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. Eisen
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuus, M., Kudryavtseva, L., Kirss, H. et al. Vapor—Liquid equilibrium for binary mixtures of isomericaln-octenes with some solvents. Monatshefte für Chemie 112, 415–420 (1981). https://doi.org/10.1007/BF00901819

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00901819

Keywords

Search

Navigation