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Die Kinetik der alkalischen Hydrolyse von m-und p-substituierten 2,4-Dinitronaphthylthiobenzoaten

The kinetics of alkaline hydrolysis of m-and p-substituted 2,4-dinitronaphthylthiobenzoates

  • Anorganische, Struktur-und Physikalische Chemie
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Abstract

The kinetics of alkaline hydrolysis of m-and p-substituted 2,4-dinitronaphthylthiobenzoates were studied. The influence of substituents on the rate of hydrolysis depends mainly on the inductive effect. Isokinetic correlation shows that all members of the series react by the same mechanism. Two typical features are firstly that the reaction constant ρ increases with temperature, and secondly that the isokinetic temperature is below that of the experiment. The kinetic treatment shows that the first step, addition of OH− to the starting compound, is the slowest and therefore rate-determining.

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Literatur

  1. L. S. Prangova, J. Y. Kvitka undL. S. Efros, Reaktionsfähigkeit der org. Verbindungen [russ.]8, 371 (1971); Chem. Abstr.76, 45363 f.

    Google Scholar 

  2. G. Morgan undE. Evens, J. Chem. Soc.115, 1128 (1919).

    Google Scholar 

  3. H. W. Talen, Rec. trav. Chim. Pays-Bas47, 784 (1928).

    Google Scholar 

  4. A. Streitwieser, Jr., Molecular Orbital Theory for Organic Chemistry. New York: Wiley. 1961.

    Google Scholar 

  5. P. H. Rieger undG. K. Frankel, J. Chem. Phys.39, 609 (1963).

    Google Scholar 

  6. R. W. Taft, J. physic. Chem.64, 1805 (1960).

    Google Scholar 

  7. V. A. Pal'm, Usp. Khim. [russ.]30, 1069 (1961).

    Google Scholar 

  8. V. A. Pal'm, Die Grundlagen der quantitativen Theorie org. Reaktionen, S. 192. Leningrad: Chemieverlag. 1967.

    Google Scholar 

  9. Y. Yukawa undJ. Tsuno, Bull. chem. Soc. Japan32, 965 (1959).

    Google Scholar 

  10. J. E. Leffler, J. Chem. Phys.25, 2199 (1955).

    Google Scholar 

  11. O. Exner, Nature201, 488 (1964).

    Google Scholar 

  12. F. Ullmann undW. Bruck, Ber. dtsch. chem. Ges.41, 3932 (1870).

    Google Scholar 

  13. L. S. Prangova, J. J. Kvitko undL. S. Efros, Dokl. Bulg. Akad. Nauk24, 1349 (1971); Chem. Abstr.76, 112332 k.

    Google Scholar 

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Authors and Affiliations

  1. Lehrstuhl für Organische Technologie, Chemischen Fakultät der Universität Sofia, 1, A. Ivanov Blvd, Sofia, Bulgarien

    Lilia S. Prangova & Stefan I. Stojanov

Authors
  1. Lilia S. Prangova
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  2. Stefan I. Stojanov
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Prangova, L.S., Stojanov, S.I. Die Kinetik der alkalischen Hydrolyse von m-und p-substituierten 2,4-Dinitronaphthylthiobenzoaten. Monatshefte für Chemie 106, 1045–1052 (1975). https://doi.org/10.1007/BF00900884

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  • DOI: https://doi.org/10.1007/BF00900884

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