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Anomalies of the electrical properties and the stability of the double layer at a metal-electrolyte boundary. Characteristics of the capacitance of a double layer with relaxing “plates∝

  • Physics of Semiconductors and Dielectrics
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Soviet Physics Journal Aims and scope

Abstract

An “electromechanical” model of the electric double layer, whose “plates” are displaced on charging, is proposed; it is shown for the example of this model that the differential capacitance can diverge and become negative. The reasons why these anomalies were not predicted in the well-known models of the double layer are examined.

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Authors and Affiliations

  1. Ural Forestry Institute, USSR

    M. B. Partenskii, Z. B. Kim & V. I. Fel'dman

Authors
  1. M. B. Partenskii
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  2. Z. B. Kim
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  3. V. I. Fel'dman
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Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 9–15, November 1987.

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Partenskii, M.B., Kim, Z.B. & Fel'dman, V.I. Anomalies of the electrical properties and the stability of the double layer at a metal-electrolyte boundary. Characteristics of the capacitance of a double layer with relaxing “plates∝. Soviet Physics Journal 30, 907–912 (1987). https://doi.org/10.1007/BF00898507

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  • DOI: https://doi.org/10.1007/BF00898507

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