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Width and shape of the vibrational spectra for the Raman scattering of chloroform in nitrobenzene and heptane solutions

  • Optics and Spectroscopy
  • Published:
Soviet Physics Journal Aims and scope

Abstract

Experimental values for the Rayleigh concentration light scattering in the nitrobenzene-chloroform solutions are smaller than the calculated ones. That means that the solution acts as a system with negative deviations from the ideal one. In the binary solutions nitrobenzene-CHCl3 the C-H vibration band in the Raman spectra shifts toward higher frequencies. In the triple mixture CHCl3-nitrobenzene-heptane a compound shape of this band is observed. The results are explained by the formation of an intermolecular hydrogen bond CHCl3-nitrobenzene.

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Authors and Affiliations

  1. Samarkand State University, Samarkand

    F. Kh. Tukhvatullin, A. K. Atakhodzhaev, S. A. Osmanov, I. P. Kleiner, A. Zhumaboev & U. N. Tashkenbaev

Authors
  1. F. Kh. Tukhvatullin
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  2. A. K. Atakhodzhaev
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  3. S. A. Osmanov
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  4. I. P. Kleiner
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  5. A. Zhumaboev
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  6. U. N. Tashkenbaev
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Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 31–33, April, 1991.

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Tukhvatullin, F.K., Atakhodzhaev, A.K., Osmanov, S.A. et al. Width and shape of the vibrational spectra for the Raman scattering of chloroform in nitrobenzene and heptane solutions. Soviet Physics Journal 34, 304–306 (1991). https://doi.org/10.1007/BF00898091

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  • DOI: https://doi.org/10.1007/BF00898091

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