Abstract
The low temperature form of Ag8GeS6 (synthetic argyrodite) is orthorhombic, space group Pna21, witha=15.149 (1),b=7.476 (2),c=10.589 (1), andZ=4. The crystal structure has been determined from 2-circle diffractometer data by means of direct methods and refined toR=0.081 for 3431 intensities. The structure consists of slightly distorted isolated GeS4 tetrahedra (mean Ge−S bond length 2.212 Å) and two further sulphur atoms without bonds to the germanium atoms. The GeS4 tetrahedra and the S atoms are connected by the Ag atoms to form a three-dimensional framework. Three types of Ag coordination by S atoms are encountered. Three Ag positions have a strongly distorted tetrahedral environment, four Ag positions an approximately planar threefold coordination, while one Ag atom is almost linearly coordinated by two S atoms. The Ag−S distances are 2.56–2.94 Å, 2.49–2.76 Å, and 2.42–2.44 Å, resp. All Ag atoms have at least one near Ag neighbour between 2.93 and 3.11 Å.
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Literatur
J. E. Hiller, Zbl. Min. Geol.A 138, 224 (1940).
C. Palache, H. Berman undC. Frondel, Danas System of Mineralogy, 7. Aufl., Vol. 1, S. 356. New York: Wiley. 1944.
H. Hahn, H. Schulze undL. Sechser, Naturwissensch.52, 451 (1965).
O. Gorochov undJ. Flahaut, C. R. hebdomad. Sé. Acad. Sci. Paris264 C, 2153 (1967).
O. Gorochov, Bull. Soc. Chim. France1968, 2263.
C. W. F. T. Pistorius undO. Gorochov, High Temperatures—High Pressures2, 31 (1970).
J. Karle, H. Hauptman undC. L. Christ, Acta cryst. [Kopenhagen]11, 757 (1958).
G. Germain, P. Main undM. M. Woolfson, Acta cryst. [Kopenhagen]B 26, 274 (1970).
G. M. Sheldrick, SHEL-X, Program System for Crystal Structure Determination, Univ. of Cambridge, 1975.
G. Germain, P. Main undM. M. Woolfson, Acta cryst. [Kopenhagen]A 27, 368 (1971).
P. A. Doyle undP. S. Turner, Acta cryst. [Kopenhagen]A 24, 390 (1968).
D. T. Cromer undJ. B. Mann, Acta cryst. [Kopenhagen]A 24, 321 (1968).
International Tables for X-Ray Crystallography, Vol. IV. Birmingham: The Kynoch Press. 1974.
K. Susa undH. Steinfink, Inorg. Chem.10, 1754 (1971).
A. Mazurier undJ. Etienne, Acta cryst. [Kopenhagen]B, 29, 817 (1972).
N. Rysanek, P. Laruelle undA. Katty, Acta cryst. [Kopenhagen]B 32, 692 (1976).
E. Philippot, M. Ribes undM. Maurin, Rév. Chim. min.8, 99 (1971).
K. Susa undH. Steinfink, J. Solid State Chem.3, 75 (1971).
E. Parthé, K. Yvon undR. H. Deitch, Acta cryst. [Kopenhagen]B 25, 1164 (1969).
G. Eulenberger, Third European Crystallographic Meeting, Zürich, 6.–10. September 1976.
H. Vincent, E. E. Bertaut, W. H. Baur undR. D. Shannon, Acta cryst. [Kopenhagen]B 32, 1749 (1976).
L. Pauling, The Nature of the Chemical Bond, 3. Aufl. Ithaca, N. Y.: Cornell University Press. 1960.
A. J. Frueh, jr., Z. Kristallogr.110, 136 (1958).
P. Engel undW. Nowacki, Neues Jb. Min., Mh.181 (1966).
A. Kutoglu, Neues Jb. Min., Mh.145 (1968).
C. R. Knowles, Acta cryst. [Kopenhagen]17, 847 (1964).
J. Mandt undB. Krebs, Z. anorg. allg. Chem.420, 31 (1976).
B. Ribár undW. Nowacki, Acta cryst. [Kopenhagen]B 26, 201 (1970).
P. Engel undW. Nowacki, Acta cryst. [Kopenhagen]B 24, 77 (1968).
R. Hesse undL. Nilson, Acta Chem. Scand.23, 825 (1969).
J. Mandt undB. Krebs, persönliche Mitteilung.
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Eulenberger, G. Die Kristallstruktur der Tieftemperaturmodifikation von Ag8GeS6 . Monatshefte für Chemie 108, 901–913 (1977). https://doi.org/10.1007/BF00898056
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DOI: https://doi.org/10.1007/BF00898056