Soviet Physics Journal

, Volume 30, Issue 10, pp 853–856 | Cite as

Theory of the rotational structure of resonant Raman scattering by diatomic molecules

  • N. F. Vasil'ev
Optics and Spectroscopy
  • 28 Downloads

Abstract

The apparatus of irreducible tensor operators is used to calculate the rotational structure of resonant Raman light scattering by freely rotating diatomic molecules. It is shown that solution of the problem reduces to the calculation of certain special coefficients. Their relation to the Placzek-Teller factors (which are well known in the theory of polarizability) is established. The nonzero coefficients are computed for the case when resonant rotational scattering is due to the1σ terms of the diatomic molecule.

Keywords

Raman Scattering Diatomic Molecule Nonzero Coefficient Tensor Operator Rotational Structure 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    K. Altmann and G. J. Strey, Molec. Phys.,44, 571 (1972).Google Scholar
  2. 2.
    Y. N. Chiu, J. Chem. Phys.,52, 3641, 4950 (1970); J. Opt. Soc. Am.,60, 607 (1970).Google Scholar
  3. 3.
    M. A. Yuratich and D. C. Hanna, Opt. Commun.,18, 134 (1976); Mol. Phys.,33, 671 (1977).Google Scholar
  4. 4.
    R. D. Sharma and L. A. Levin, J. Chem. Phys.,58, 1660 (1973).Google Scholar
  5. 5.
    L. D. Landau and E. M. Lifshitz, Quantum Mechanics, Pergamon Press, Oxford (1974).Google Scholar
  6. 6.
    V. B. Berestetskii, E. M. Lifshitz, and L. P. Pitaevskii, Relativistic Quantum Theory, Part 1, Pergamon Press, Oxford (1971).Google Scholar
  7. 7.
    G. Placzek and E. Teller, Z. Physik,83, 209 (1933).Google Scholar
  8. 8.
    D. A. Varshalovich, A. N. Moskalev, and V. K. Khersonskii, Quantum Theory of Angular Momentum [in Russian], Nauka, Leningrad (1975).Google Scholar
  9. 9.
    J. A. Koningstein, Introduction to the Theory of the Raman Effect, Reidel, Dordrecht, Holland (1972).Google Scholar
  10. 10.
    L. S. Aslanyan and N. I. Koroteev, Kvantovaya Elektron.,6, 942 (1979).Google Scholar
  11. 11.
    V. A. Morozov, Opt. Spektrosk.,18, 198 (1965);19, 35 (1965).Google Scholar
  12. 12.
    M. Jacon and D. Van Labeke, Molec. Phys.,29, 1241 (1975).Google Scholar

Copyright information

© Plenum Publishing Corporation 1988

Authors and Affiliations

  • N. F. Vasil'ev
    • 1
  1. 1.V. D. Kuznetsov Physicotechnical Institute at Tomsk State UniversityUSSR

Personalised recommendations