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Soviet Physics Journal

, Volume 28, Issue 3, pp 234–237 | Cite as

Perturbation theory for a mixture of polarizable liquids

  • A. P. Ugol'nikov
Physics of Liquids and Gases

Abstract

Thermodynamic perturbation theory developed for pure polar liquids with significant polarizability is applied to a mixture with polar and nonpolar polarizable components. Expressions for the average and unperturbed dipole moments of the components of the mixture are presented and the dipole and induced contributions to the thermodynamic functions of the mixture are calculated. The equation of state is obtained and used to calculate the excess properties of a binary mixture of particles interacting with a stockmeyer potential. It is shown that the induced dipole moments contribute significantly to the thermodynamic properties of this model solution and that their effects must be taken into account in predicting the properties of real liquid mixtures containing polar components.

Keywords

Dipole Moment Perturbation Theory Thermodynamic Property Binary Mixture Model Solution 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    A. P. Ugol'nikov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 9, 55 (1983).Google Scholar
  2. 2.
    S. V. Tyablikov, Methods of the Quantum Theory of Magnetism [in Russian], Nauka, Moscow (1965).Google Scholar
  3. 3.
    S. Kelikh, Molecular Nonlinear Optics [in Russian], Nauka, Moscow (1981).Google Scholar
  4. 4.
    S. A. Adelman and J. M. Deutch, J. Chem. Phys.,59, No. 8, 3971 (1973).Google Scholar
  5. 5.
    L. Verlet and J. Weis, J. Mol. Phys.,28, No. 3, 665 (1974).Google Scholar
  6. 6.
    F. H. Ree, J. Chem. Phys.,73, No. 10, 5401 (1980).Google Scholar
  7. 7.
    B. Larsen, J. C. Rasaiah, and G. Stell, Mol. Phys.,33, No. 4, 987 (1977).Google Scholar

Copyright information

© Plenum Publishing Corporation 1985

Authors and Affiliations

  • A. P. Ugol'nikov
    • 1
  1. 1.Odessa Technical Institute of the Refrigeration IndustryUSSR

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