Skip to main content
Log in

Mechanism of structural dielectric relaxation in associated liquids

  • Published:
Soviet Physics Journal Aims and scope

Abstract

A mechanism of structural dielectric relaxation is proposed, and on this basis the kinetic equations taking into account tunneling of protons from the clusters are written and investigated. The solution, together with the results of dielectric measurements, is used to determine the structural parameters of low-concentration aqueous solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. G. Nemethy and H. A. Scheraga, J. Chem. Phys.,36, 3382 (1962).

    Google Scholar 

  2. W. P. Mason (editor), Physical Acoustics, Academic Press (1965).

  3. Ya. I. Frenkel', Kinetic Theory of Liquids, Peter Smith.

  4. M. P. Tonkonogov, V. A. Veksler, and K. Zh. Birzhanov, Zh. Fiz. Khim.,49, 1203 (1975).

    Google Scholar 

  5. V. F. Nozdrev and N. V. Fedorishchenko, Molecular Acoustics [in Russian], Vysshaya Shkola, Moscow (1974).

    Google Scholar 

  6. M. P. Tonkonogov, V. A. Veksler, and K. Zh. Birzhanov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 2, 73 (1975).

    Google Scholar 

  7. M. I. Shakhparonov, Introduction to the Modern Theory of Solutions [in Russian], Vysshaya Shkola, Moscow (1976).

    Google Scholar 

  8. R. P. Bell, The Proton in Chemistry, Cornell Univ. Press (1973).

  9. V. I. Gol'danskii, Usp. Khim.,44, 2121 (1975).

    Google Scholar 

  10. A. M. Blokh, Water Structure and Geological Processes [in Russian], Nedra, Moscow (1969).

    Google Scholar 

  11. M. P. Tonkonogov, V. A. Veksler, and K. Zh. Birzhanov, Zavod. Lab.,9, 1107 (1975).

    Google Scholar 

  12. T. Erden-Gruz, Transfer Phenomena in Aqueous Solutions [Russian translation], Mir, Moscow (1976).

    Google Scholar 

  13. R. A. Home, Marine Chemistry, Wiley (1969).

  14. K. P. Mishchenko and G. M. Poltoratskii, Thermodynamics and Structure of Aqueous and Nonaqueous Electrolyte Solutions [in Russian], Khimiya, Leningrad (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 16–19, November, 1979.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tonkonogov, M.P., Veksler, V.A., Birzhanov, K.Z. et al. Mechanism of structural dielectric relaxation in associated liquids. Soviet Physics Journal 22, 1136–1139 (1979). https://doi.org/10.1007/BF00894958

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00894958

Keywords

Navigation