Abstract
Solutions of the Bogolyubov-Born-Green-Kirkwood-Ivon equations in the fourth approximation in the temperature are given in a class of generalized functions both for van der Waals and ionic crystals in the case of the so-called taking into account of “smoothed” correlations. A statistical thermodynamics of strongly anharmonic van der Waals and ionic crystals is constructed. Temperature expansions of the correlative distribution functions and thermodynamic quantities are investigated within the framework of the indicated method. The temperature dependence of cubic order is taken into account in the expression of the isochoric specific heat and the Grüneisen parameter of the listed crystals. It is shown that the temperature expansion for the isochoric specific heat of anharmonic crystals converges well for a value of the reduced temperature ≈ 0.33 Tm (Tm is the melting temperature).
Similar content being viewed by others
Literature cited
I. I. Ol'khovskii, Dokl. Akad. Nauk SSSR,208, 808 (1973);221, 1063 (1975); Teor. Mat. Fiz.,15, 382 (1973);23, 399 (1975); Izv. Vyssh Uchebn. Zaved., Fiz., No. 1, 14 (1976).
I. I. Ol'khovskii and V. L. Ékelekyan, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 11, 60 (1976).
I. I. Ol'khovskii and V. L. Ékelekyan, Izv. Vyssh. Uchebn, Zaved., Fiz., No. 11,86, 92 (1975); No. 10, 129 (1976).
I. I. Ol'khovskii and V. L. Ékelekyan, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 4, 44 (1976).
N. N. Bogolyubov, Collected Works [in Russian], Vol. 2, Kiev (1970).
D. C. Wallace and J. L. Patrick, Phys. Rev.,137, A152 (1965); J. E. Jones and A. E. Ingham, Proc. Roy. Soc.,A107, 636 (1925).
P. Ewald, Ann. Phys.,64, 250 (1921).
G. Leibfried and V. Ludwig, Theory of Anharmonic Effects in Crystals [Russian translation], Inostr. Lit., Moscow (1963).
V. A. Golovko, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 12, 85 (1978); No. 2, 67 (1979).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 55–59, July, 1981.
Rights and permissions
About this article
Cite this article
Ékelekyan, V.L. Solutions of the BBGKI equations in the fourth approximation in the temperature. Soviet Physics Journal 24, 626–630 (1981). https://doi.org/10.1007/BF00893895
Issue Date:
DOI: https://doi.org/10.1007/BF00893895