Conclusions
Solution of the salt Zr(SO4)2 leads to a long-wave shift of the extrema of the Kronig structure in the x-ray K absorption spectrum of zirconium. Primary and secondary hydration both make a contribution to the shift. The magnitude of the shifts increases with increasing distance into the short-wave region from the K edge and is due to an increase in the distance of the zirconium atom from its immediate environment.
Similar content being viewed by others
Literature cited
A. Ganson, J. Phys. et Radium,22, No. 5, 298 (1961).
A. I. Kostarev, Zh. Éksp. Teor. Fiz.,11, 60 (1941).
A. I. Kozlenkov, Izv. Akad. Nauk SSSR, Ser. Fiz.,25, 975 (1961).
T. Shiraiwa, T. Ishimura, and M. Sawada, J. Phys. Soc. Japan,13, 847 (1958).
D. A. Rogachev, A. S. Antsyshkina, and M. A. Porai-Koshits, Zh. Strukt. Khim.,10, No. 4, 645 (1969).
M. A. Blokhin, Methods of X-Ray Spectroscopic Research [in Russian], Fizmatgiz, Moscow (1959).
R. M. Levy and I. R. Wazer, Advan. Anal. Chem. Instr.,5, 221 (1966).
V. A. Mikhailov and S. I. Drakin, Izv. SO AN SSSR, No. 6, 44 (1960).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 120–122, October, 1972.
Rights and permissions
About this article
Cite this article
Petrov, É.V. X-ray K absorption spectrum of zirconium in crystalline hydrate Zr(SO4)2·nH2O. Soviet Physics Journal 15, 1488–1490 (1972). https://doi.org/10.1007/BF00892102
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00892102