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Stratospheric methane and nitrogen dioxide from infrared spectra

  • Observational Results on Other Trace Substances
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Abstract

Values of the mixing ratio by volume of stratospheric NO2 and CH4 deduced from infrared spectra taken by means of balloon-borne spectrometers are presented. Possible evidence for the presence of formaldehyde in the stratosphere is also given.

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References

  1. M. Ackerman,Aeronomical balloon experiments, Space Sci. Rev.13 (1972), 290–294.

    Article  Google Scholar 

  2. M. Ackerman andD. Frimout,Mesure de l'absorption stratosphérique du rayonnement solaire de 3,05 à 3,7 microns, Bull. Acad. Roy. Belgique, Cl. Sc.55 (1969), 948–954.

    Google Scholar 

  3. A. E. Bainbridge andL. E. Heidt,Measurements of methane in the troposphere and lower stratosphere, Tellus18 (1966), 221–225.

    Article  Google Scholar 

  4. W. S. Benedict andR. F. Calfee, Line Parameters for the 1.9 and 6.3 Micron Water Vapor Bands, ESSA Professional Paper 2, U.S. Department of Commerce, Washington, D.C. (1967).

    Google Scholar 

  5. R. E. Blank, M. D. Olman andC. D. Hause,Upper state molecular constants for the (0, 0, 3) and (1, 0, 3) vibration-rotation bands of nitrogen dioxide, J. Mol. Spect.33 (1970), 109–118.

    Article  Google Scholar 

  6. G. Brasseur andS. Cieslik,On the behavior of nitrogen oxides in the stratosphere, Pure and Appl. Geophys.106–108 (1973) 1431.

    Article  Google Scholar 

  7. D. E. Burch andD. Williams, Infrared Absorption by Nitrous Oxide, Carbon Monoxide and Methane, Research Report AF 19 (604)-2633 (1962).

  8. R. S. Drayson,Atmospheric transmission in the CO 2 bands between 12 and 18 μ, Appl. Opt.5 (1966), 385–391.

    Article  Google Scholar 

  9. D. H. Ehhalt, L. E. Heidt andE. A. Martell,The concentration of atmospheric methane between 44 and 62 kilometers altitude, J. Geophys. Res.77 (1972), 2193–2196.

    Article  Google Scholar 

  10. U. Fink, R. H. Rank andT. A. Wiggins,Abundance of methane in the earth's atmosphere, J. Opt. Soc. Amer.54 (1964), 472–474.

    Article  Google Scholar 

  11. A. Goldman, D. G. Murcray, F. H. Murcray, W. Williams andF.S. Bonomo, Identification of the ν3 No2 band in the solar spectrum by means of a balloon-borne spectrometer, Nature225 (1970), 443–444.

    Article  Google Scholar 

  12. F. W. P. Gotz,Bandes atmosphériques dans l'ultraviolet, Archs Sci. phs. nat. Genève139 (1934), 266–268.

    Google Scholar 

  13. A. Guttman,Absolute infrared intensity measurements on nitrogen dioxide and dinitrogen tetroxide, J.Q.S.R.T.2 (1962), 1–15.

    Google Scholar 

  14. J. E. Harries, N. R. W. Swann, J. E. Beckman andP. A. R. Ade,High resolution observations of the submillimetre stratospheric emission spectrum, Nature236 (1972), 159–161.

    Article  Google Scholar 

  15. J. T. Houghton, N. D. P. Hughes, T. S. Moss andJ. S. Seeley,An atlas of the infrared solar spectrum from 1 to 6.5 μ observed from a high-altitude aircraft, Phil. Trans. Roy. Soc. (London), Ser. A254 (1961), 47–123.

    Article  Google Scholar 

  16. T. G. Kyle, Line Parameters of the Infrared Methane Bands, Scientific Report A.F. 19 (628)-5706 (1968).

  17. T. G. Kyle,Net interval for calculating absorption spectra, J. Opt. Soc. Amer.58 (1968), 192–195.

    Article  Google Scholar 

  18. J. McMahon, G. J. Troup, G. Hubert andT. G. Kyle The effect of pressure and temperature on the half-width of the methane absorption at 3.39 μ, J.Q.S.R.T.12 (1972), 797–805.

    Google Scholar 

  19. M. Migeotte,Spectroscopic evidence of methane in the earth's atmosphere, Phys. Rev.73 (1948), 519.

    Article  Google Scholar 

  20. M. Nicolet Aeronomic reactions of hydrogen and ozone, inMesopheric Models and Related Experiments (Reidel Publ. Cy., Dordrecht 1971), pp. 1–51.

    Google Scholar 

  21. M. Nicolet andW. Peetermans On the vertical distribution of carbon monoxide and methane in the stratosphere, Pure and Appl. Geophys.106–108 (1973), 1400.

    Article  Google Scholar 

  22. M. D. Olman andC. D. Hause Molecular constants of nitrogen dioxide from the near infrared spectrum, J. Mol. Spect.26 (1968), 241–253.

    Article  Google Scholar 

  23. R. H. Pierson, A. N. Fletcher andE. St. Clair Gantz,Catalogue of infrared spectra for qualitative analysis of gases, Anal. Chem.28 (1956), 1218–1239.

    Article  Google Scholar 

  24. G. N. Plass andD. I. Fivel,Influence of Doppler effect on line-absorption coefficient and atmospheric radiation transfer, Ap. J.117 (1953), 225–233.

    Article  Google Scholar 

  25. F. W. Taylor, Methods and approximations for the computation of transmission profiles in the ν4 band of methane in the atmosphere of Jupiter, J.Q.S.R.T.12 (1972), 1151–1156.

    Google Scholar 

  26. P. Varanasi andG. D. T. Tejwani, Experimental and theoretical studies on collision broadened lines in the ν4 fundamental of methane, J.Q.S.R.T.12 (1972), 849–855.

    Google Scholar 

  27. B. H. Winters, S. Silverman andW. S. Benedict,Line shape in the wings beyond the band head of the 4.3 μ band of CO 2, J.Q.S.R.T.4 (1964), 527–537.

    Google Scholar 

  28. K. Yamada, T. Nakagawa andY. Morino, Band contour analysis of the ν1 and ν2 fundamentals of formaldehyde, J. Mol. Spect.38 (1971), 70–83.

    Article  Google Scholar 

  29. G. Yamamoto andT. Aoki,Line broadening theory of asymmetric-top molecules, J.Q.S.R.T.12 (1972), 227–241.

    Google Scholar 

  30. G. Yamamoto andM. Hirono,Rotational line width of methane, J.Q.S.R.T.,11 (1971), 1537–1545.

    Google Scholar 

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Ackerman, M., Muller, C. Stratospheric methane and nitrogen dioxide from infrared spectra. PAGEOPH 106, 1325–1335 (1973). https://doi.org/10.1007/BF00881086

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