Abstract
In this paper it is proposed to quantify the importance of some physical parameters responsible for stone decay on monuments. The most common decay process is the crystallisation of salt near the surface of the rocks or inside their porous network. Therefore, the water balance in rocks submitted to these special saturation and position conditions has been studied specifically, using the general concepts of water transfer in unsaturated porous media, and using the capillary imbibition kinetics of different rocks. Different parameters have been taken into account for the calculation of the salt crystallisation position: on one hand, several external parameters such as relative humidity, air convection and the presence of solute in solution, and on the other hand, the intrinsic water transfer properties of the rocks. Their relative importance is discussed, considering the potential values that each parameter can reach in nature.
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References
Acheson, D. T.,Vapor Pressure of Saturated Aqueous Salt Solutions. Humidity and Moisture (Rheinhold Publ. Corp., New York 1963)3, 521–530.
Amoroso, G. G., andFassina, V. (1983),Stone Decay and Conservation, Materials Science Monograph11, Elsevier, 453 pp.
Arnold, A. (1976),Behaviour of Some Soluble Salts in Stone Deterioration, 2nd Internat. Symp. on the Deterioration of Building Stones, Athens, 27–36.
Bond, J. J., andWillis, W. O. (1969),Soil Water Evaporation: Surface Residue Rate and Placement Effects, Soil Sci. Soc. Am. Proc.33, 445–448.
Brunel, J. P., andBouron, B. (1992),Evaporation des nappes d'eau libres en Afrique Sahelienne et Tropicale, Document CIEH-ORSTOM, Oct. 1992, 402 pp.
Childs, E. C., andCollis-George, N. (1950),The Permeability of Porous Materials, Proc. Roy. Soc.201A, 392–405.
Debye, P., andHuckel, E. (1923).Zur Theorie der Electrolyte. Phys. Z.24, 185–208.
Debye, P., andHuckel, E. (1923).Zur Theorie der Electrolyte, Phys. Z.24, 305–325.
Dullien, F. A. L.,Porous Media—Fluid Transport and Pore Structure (Academic Press, New York 1979) 396 pp.
Dullien, F. A. L., Zarcone, C., Macdonald, I. F., Collins, A., andBochard, R. D. E. (1988).The Effects of Surface Roughness on the Capillary Pressure Curves and the Heights of Capillary Rise in Glass Bead Packs, J. Colloid and Interface Sci.127 (2), 362–372.
Gardner, W. R. andMayhugh, M. S. (1958),Solutions and Tests of the Diffusion Equation for the Movement of Water in Soil. Soil Sci. Soc. Am. Proc.22, 197–201.
Gardner, W. R., andHillel, D. L. (1962),The Relation of External Evaporative Conditions to the Drying of Soils, J. Geophys. Res.67 (11), 4319–4325.
De Groot, S. R., andMazur, P.,Nonequilibrium Thermodynamics (North-Holland Publ. Co., Amsterdan 1962).
Hallaire, M., andHenin, S. (1958).Dessèchement du sol et évolution des profils hydriques. C. R. Acad. Sci.46, 2151–2153.
Hammecker, C., andJeannette, D. (1988),Rôle des propriété physiques dans l'altération de roches carbonatées: Exemple de la façade ouest de Notre-Dame-La Grande de Poitiers (France), Proc. VIth Int. Cong. on Deterioration and Conservation of Stone, Torun (Poland), 266–275.
Hammecker, C., (1993),Importance des transferts d'eau dans la dégradation des pierres en oeuvre, Ph.D. Thesis, Université Louis Pasteur, Strasbourg.
Hammecker, C., Mertz, J. D., Fischer, C., andJeannette, D. (1993).A Geometrical Model for Numerical Simulation of Capillary Imbibition in Sedimentary Rocks. Transport in Porous Media12 (3), 125–141.
Hammecker, C., andJeannette, D. (1994),Modelling the Capillary Imbibition in Sedimentary Rocks: Role of Petrographical Features, Transport in Porous Media17 (3), 285–303.
Harvie, C. E., andWeare, J. H. (1980),The Prediction of Mineral Solubilities in Natural Waters: The Na−K−MG−Ca−Cl−SO 4−H2O System from Zero to High Concentration at 25°C, Geochim. Cosmochim. Acta44, 981–997.
Hillel, D.,Soil and Water—Physical Principles and Processes (Adacemic Press, Inc., Orlando 1971) 299 pp.
Jouany, C. (1981),Transfert d'eau par évaporation dans les milieux argileux, Ph.D. Thesis, Université Paul Sabatier, Toulouse, 102 pp.
Jeannette, D., andHammecker, C.,Facteurs et mécanismes des altérations. InLa conservation de la pierre monumentale on France (Presses du CNRS 1992) pp. 73–81.
Jeannette, D., andHammecker, C. (1993),Importance des structures de porosité dans l'altération des pierres des monuments, Coll. Sédimentologie et Géochimie de la Surface, à la Mém. de G. Millot, Les Coll. de L'Acad. des Sci. et Cadas., 307–319.
Levine, S., Lowndes, J., andReed, P. (1980),Two Phase-fluid Flow and Hysteresis in a Periodic Capillary Tube, J. Colloid. Interface Sci.77, 253–263.
Pearse, J. F., Oliver, T. R., andNewitt, D. M. (1949),The Mechanisms of Drying of Solids: I. The Forces giving Rise to Movement of Water in Granular Beds during Drying, Trans. Inst. Chem. Eng., London27, 1–8.
Pitzer, K. S. (1973),Thermodynamics of Electrolytes I: Theoretical Basis and General Equations, J. Phys. Chem77, 268–2777.
Pitzer, K. S.,Theory: Ion interaction approach. InActivity Coefficients in Electrolyte Solutions, 1 (ed. Pytkowicz, R. M.) (CRC Press 1979)77, 157–208.
Robie, R., Hemingway, B., andFischer, J. (1978),Thermodynamic Properties of Minerals and Related Substances at 298.15°K and 1 bar (105 Pascals)Pressure and at Higher Temperatures, U.S. Geol. Surv. Bull.1452, 456 pp.
Schünder, E. U.,A simple procedure for measurement of vapor pressure over aqueous salt solutions—In Humidity and Moisture (Rheinhold Publ. Corp., New York 1963)3, pp. 535–544.
Swartzendruber, D.,The flow of water in unsaturated soils. InFlow Through Porous Media (ed. De Wiest) (Academic Press, New York 1969) pp. 215–292.
Szekely, J., Neumann, A. W., andChuang, Y. K. (1971),The Rate of Capillary Penetration and the Applicability of the Washburn Equation, J. Colloid Interface Sci.35, 273–283.
De Vries, D. A., andKruger, A. J. (1967),On the value of diffusion coefficient of water vapour in air. InPhénomènes de transport avec changement de phase dans les milieux poreux colloïdaux, Ed. CNRS,160, 61–72.
Washburn, E. W. (1921),The Dynamic of Capillary Flow, Phys. Rev.17, 273–283.
Winkler, E. M., andSinger, P. C. (1972),Crystallization Pressure of Salts in Stone and Concrete, Geol. Soc. Am. Bull.83, 3509–3514.
Wylie, R. G.,The properties of salt-water systems in relation humidity. InHumidity and Moisture, (Rheinhold Publ. Corp., New York 1963)3, pp. 507–517.
Zehnder, K. (1982),Verwitterung von Molassesandsteinen an Bauwerken und in Naturaufschlüssen, Beiträge z. Geologie d. Schweiz, Geotech. Kommission61, Kümmerly and Frey, Bern.
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Hammecker, C. The importance of the petrophysical properties and external factors in the stone decay on monuments. PAGEOPH 145, 337–361 (1995). https://doi.org/10.1007/BF00880275
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DOI: https://doi.org/10.1007/BF00880275