Abstract
On the basis of an equation proposed previously, a method for calculating the isotherms of water-vapor sorption by swelling hydrophilic sorbents is outlined. The construction of the isotherms entails some information on the physicochemical characteristics of the system — for example, the binding energy of the sorbate molecule with the active center, the degree of hydration of the sorbent, the temperature, the sorptional centers and their mutual position, etc. As an example, the calculation of the isotherms of water-vapor sorption by cotton is considered.
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B. P. Bering and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., No. 11, 2427–2440 (1974).
B. P. Bering, V. V. Serpinskii, and T. S. Yakubov, Adsorbents, Their Preparation, Properties, and Application [in Russian], Leningrad (1978).
Yu. K. Tovbin, Theory of Physicochemical Processes at a Gas-Solid Boundary [in Russian], Moscow (1990).
N. I. Gamayunov and A. V. Tvardovskii, Inzh.-Fiz. Zh.,41, No. 5, 854–858 (1981).
N. I. Gamayunov and A. V. Tvardovskii, Zh. Fiz. Khim.,60, No. 12, 3011–3015 (1986).
N. I. Gamayunov and A. V. Tvardovskii, Inzh.-Fiz. Zh.,51, No. 4, 533–536 (1986).
V. I. Kasatochkin and A. G. Pasynskii, Physical and Colloidal Chemistry [in Russian], Moscow (1960).
N. I. Gamayunov and A. V. Tverdovskii, Zh. Fiz. Khim.,55, No. 6, 1599–1601 (1981).
N. I. Gamayunov and B. V. Evdokimov, in: Physicochemical Mechanics and Lyophilic Character of Disperse Systems [in Russian], No. 11, 55–62 (1979).
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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 59, No. 5, pp. 776–779, November, 1990.
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Gamayunov, N.I., Tvardovskii, A.V. Isotherms of the sorption of water vapor by swelling hydrophilic sorbents. Journal of Engineering Physics 59, 1405–1408 (1990). https://doi.org/10.1007/BF00872957
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DOI: https://doi.org/10.1007/BF00872957