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Effect of interion interactions on electrolyte properties near a phase separation boundary

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Abstract

The interaction of ions in solution and in the adsorbed state with themselves and with charges induced in the solid phase varies the isotherms of ion adsorption and the structure of the diffusion part of a double electric layer. This effect is treated within the Debye-Huckel approximation for a dilute solution of a strong electrolyte under conditions of local thermodynamic equilibrium.

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Translated from Inzhenerno-fizicheskii Zhurnal, Vol. 61, No. 4, pp. 586–597, October, 1991.

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Buevich, Y.A., Siziya, S.V. Effect of interion interactions on electrolyte properties near a phase separation boundary. Journal of Engineering Physics 61, 1225–1234 (1991). https://doi.org/10.1007/BF00872590

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  • DOI: https://doi.org/10.1007/BF00872590

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