Organometallic synthesis in the furazan series 1. Functionalization of 3-methyl-4-R-furazans

  • A. Yu. Sizov
  • A. B. Sheremetev
Organic Chemistry Methods Of Synthesis

Abstract

The possibility of synthesizing functionally substituted furazans by alkylation of lithium derivatives of 3-methyl-4-R-furazans was investigated. It was shown that one or both methyl groups of 3,4-dimethylfurazan could be lithiated and alkylated. A series of previously unknown furazan derivatives was obtained.

Keywords

furazan lithiation alkylation 

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Literature cited

  1. 1.
    A. Yu. Sizov and A. B. Sheremetev, Proceedings of the Fifth Moscow Conference on Organic Chemistry and Technology, Moscow (1989), p. 209.Google Scholar
  2. 2.
    R. M. Paton, in: Comprehensive Heterocyclic Chemistry, A. R. Katrikzky and C. W. Rees (eds.), Vol. 6, Pergamon, Oxford (1984), p. 393.Google Scholar
  3. 3.
    L. C. Behr, Chem. Heterocycl. Comp.,17, 283 (1962).Google Scholar
  4. 4.
    D. Boyer, Heterocyclic Compounds, Vol. 7 [Russian translation]. Mir, Moscow (1965), p. 357.Google Scholar
  5. 5.
    K. L. Stuart, Heterocycles,3, 651 (1975).Google Scholar
  6. 6.
    W. Sliva, Heterocycles,22, 1571 (1984).Google Scholar
  7. 7.
    B. A. Tertov and Yu. V. Koshchienko, Khim. Geterotsikl. Soedin., No. 2, 147 (1988).Google Scholar
  8. 8.
    I. V. Tselinskii, S. F. Mel'nikova, S. N. Vergizov, and G. M. Frolova, Khim. Geterotsikl. Soedin., No. 1, 35 (1981).Google Scholar
  9. 9.
    R. G. Micetich, Canad. J. Chem.,48, 2006 (1970).Google Scholar
  10. 10.
    R. A. Olofson and J. S. Michelman, J. Org. Chem.,30, 1854 (1965).Google Scholar
  11. 11.
    N. S. Vul'fson, V. G. Zaikin, and A. I. Mikaya, Mass Spectrometry of Organic Compounds [in Russian], Khimiya, Moscow (1986), p. 110.Google Scholar

Copyright information

© Plenum Publishing Corporation 1992

Authors and Affiliations

  • A. Yu. Sizov
  • A. B. Sheremetev

There are no affiliations available

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