Diacetylene derivatives

Communication 19. Some transformations of alkoxy-and alkylthioenynic alcohols of the aliphatic series
  • A. N. Nikol'skaya
  • A. V. Bogdanova
  • T. L. Kovtonogova
  • A. N. Volkov
Organic and Biological Chemistry
  • 19 Downloads

Conclusions

  1. 1.

    1-Alkoxy-5-hydroxy-1-alken-3-ynes under acid hydrolysis conditions are converted to acetylenic aldehydoalcohols, which isomerize to olefinic ketoaldehydes.

     
  2. 2.

    A study was made of the reaction for the free-radical addition of mercaptans to 1-alkylthio-5-hydroxy-1-alken-3-ynes, which made it possible to obtain actylenic and olefinic hydroxymercaptals.

     

Keywords

Hydrolysis Acid Hydrolysis Diacetylene Mercaptan Hydrolysis Condition 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    A. V. Bogdanova, A. N. Dolgikh, and M. F. Shostakovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 359, 363 (1965).Google Scholar
  2. 2.
    A. N. Volkov, A. V. Bogdanova, and G. P. Kugatova-Shemyakina, Zh. Organ. Khim.,3, 316 (1967).Google Scholar
  3. 3.
    A. V. Bogdanova, G. P. Kugatova-Shemyakina, T. M. Ushakova, and G. I. Kozub, Zh. Organ. Khim.,3, 673 (1967).Google Scholar
  4. 4.
    A. N. Volkov, A. V. Bogdanova, A. N. Dolgikh, and M. F. Shostakovskii, in: Acetylene Chemistry [in Russian], Nauka (1968), p. 29.Google Scholar
  5. 5.
    T. Herbertz, Chem. Ber.,85, 475 (1952).Google Scholar
  6. 6.
    B. P. Gusev and V. F. Kuchernov, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1067 (1962).Google Scholar
  7. 7.
    A. V. Bogdanova, M. F. Shostakovskii, and G. I. Plotnikova, Dokl. Akad. Nauk SSSR,124, 107 (1959).Google Scholar
  8. 8.
    E. N. Prilezhaeva, L. V. Tsymbal, and M. F. Shostakovskii, Zh. Obsheh. Khim.,31, 2487 (1961).Google Scholar
  9. 9.
    M. F. Shostakovskii, E. N. Prilezhaeva, and N. I. Uvarova, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 526 (1954).Google Scholar
  10. 10.
    M. F. Shostakovskii, E. P. Gracheva, and N. K. Kul'bovskaya, Usp. Khim.,30, 493 (1961).Google Scholar
  11. 11.
    A. V. Bogdanova, M. F. Shostakovskii, and G. I. Plotnikova, Dokl. Akad. Nauk SSSR,120, 301 (1958).Google Scholar
  12. 12.
    B. P. Gusev and V. F. Kucherov, Izv. Akad. Nauk SSSR, Ser. Khim., 1318 (1964).Google Scholar

Copyright information

© Consultants Bureau 1971

Authors and Affiliations

  • A. N. Nikol'skaya
    • 1
  • A. V. Bogdanova
    • 1
  • T. L. Kovtonogova
    • 1
  • A. N. Volkov
    • 1
  1. 1.Irkutsk Institute of Organic ChemistrySiberian Branch of the Acedemy of Sciences of the USSRUSSR

Personalised recommendations