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Synthesis and isomerization of alkylthiosulfolenes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A laboratory method for the synthesis of 3-chlorosulfol-3-ene has been developed.

  2. 2.

    The replacement of chlorine by a t-butyl group takes place without isomerization only in diglyme. In alcohol the 3-t-butylthiosulfol-3-ene formed initially is converted almost completely into 3-t-butyl-thiosulfol-2-ene.

  3. 3.

    The high-temperature decomposition of 3-t-butylthiosulfol-3-ene has given the previously-unknown 2-t-butylthiobuta-1,3-diene.

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Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSSR, USSR

    E. N. Prilezhaeva, V. N. Petrov, V. A. Sil'ke & A. V. Kessenikh

Authors
  1. E. N. Prilezhaeva
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  2. V. N. Petrov
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  3. V. A. Sil'ke
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  4. A. V. Kessenikh
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2223–2225, December, 1966.

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Prilezhaeva, E.N., Petrov, V.N., Sil'ke, V.A. et al. Synthesis and isomerization of alkylthiosulfolenes. Russ Chem Bull 15, 2155–2157 (1966). https://doi.org/10.1007/BF00867724

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  • DOI: https://doi.org/10.1007/BF00867724

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