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Copper-stearate-catalyzed oxidation of α-naphthylamine with oxygen

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

The oxidation ofα- naphthylamine with molecular oxygen in chlorobenzene and in the presence of copper stearate takes place through the formation of a ternary amine-copper-oxygen complex. The oxidation of the amine in the complex takes place with an activation energy of 14.7 kcal/mole and an activation entropy of −35.3 entropy units.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    L. N. Denisova & E. T. Denisov

Authors
  1. L. N. Denisova
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  2. E. T. Denisov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2220–2223, December, 1966.

The authors express their thanks to A. E. Krylova for taking the IR spectra and to S. A. Gancho for help in carrying out the experiments.

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Denisova, L.N., Denisov, E.T. Copper-stearate-catalyzed oxidation of α-naphthylamine with oxygen. Russ Chem Bull 15, 2152–2154 (1966). https://doi.org/10.1007/BF00867723

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  • DOI: https://doi.org/10.1007/BF00867723

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