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Synthesis and properties of some ethynylchlorosilanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method was proposed for synthesizing ethynylchlorosilanes by thermal gas-phase interaction of dichloroethylene and chlorosilicon hydrides.

  2. 2.

    The triple bond of ethynylchlorosilanes is capable of adding bromine, hydrogen bromide, and thiophenol; moreover, hydrogen bromide is added “counter to the Markovnikov rule.”

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Authors and Affiliations

  1. N. D. Zelinskii Institute or Organic Chemistry, Academy of Sciences of the USSR, USSR

    E. A. Chernyshev & G. F. Pavelko

Authors
  1. E. A. Chernyshev
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  2. G. F. Pavelko
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2205–2207, December, 1966.

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Chernyshev, E.A., Pavelko, G.F. Synthesis and properties of some ethynylchlorosilanes. Russ Chem Bull 15, 2131–2133 (1966). https://doi.org/10.1007/BF00867715

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  • DOI: https://doi.org/10.1007/BF00867715

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