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Reactions of methanol and ethanol with tetrachloroethylene

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    Reaction between methanol and tetrachloroethylene at a molar ratio of 4 ∶ 1 at 570° leads to the formation of 2,3,3-trichloro-2-propen-1-ol in 25–35% yield.

  2. 2.

    In the reaction of ethanol with tetrachloroethylene 3,4,4-triehloro-3-buten-2-ol and 1,1,2,3-tetrachloropropene were studied. A number of substances containing the trichlorovinyl group and of potential interest as herbicides were prepared.

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Literature cited

  1. G. I. Nikishin, Izv. AN SSSR Otd. khim. n. 1959, 1134.

  2. Yu. P. Egorov and E. D. Lubuzh, Dokl. AN SSSR,136, 342 (1961).

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  5. A. N. Nesmeyanov, V. N. Kost, L. I. Zakharkin, and R. Kh. Freidlina, Izv. AN SSSR, Otd. khim. n. 1960, 447.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    G. I. Nikishin, M. I. Dyusenov & G. V. Somov

Authors
  1. G. I. Nikishin
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  2. M. I. Dyusenov
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  3. G. V. Somov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2188–2192, December, 1966.

Spectra were determined by E. D. Lubuzh, whom we thank.

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Nikishin, G.I., Dyusenov, M.I. & Somov, G.V. Reactions of methanol and ethanol with tetrachloroethylene. Russ Chem Bull 15, 2115–2119 (1966). https://doi.org/10.1007/BF00867711

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  • DOI: https://doi.org/10.1007/BF00867711

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