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Telomerization of octamethylcyclotetrasiloxane with dichloromethyl (3,3,3-trif luoropropyl) silane and with chlorotris (3,3,3-trif luoropropyl) silane

  • V. A. Ponomarenko
  • N. M. Khomutova
Organic and Biological Chemistry

Conclusions

  1. 1.

    The telomerization of octamethylcyclotetrasiloxane with fluorinated alkylchlorosilanes was investigated for the first time. The telomerization of octamethylcyclotetrasiloxane with dichloromethyl (3,3,3-trifluoropropyl) silane and with chlorotris (3,3,3-trifluoropropyl) silane leads to the formation of linear structure.

     
  2. 2.

    The telomerization of octamethylcyclotetrasiloxane with chlorotris (3,3,3-trifluoropropyl) silane is accompanied by a side reaction in which terminal groups of the telomer are eliminated with formation of hexakis (3,3,3-trifluoropropyl) disiloxane.

     

Keywords

Silane Side Reaction Linear Structure Terminal Group Telomerization 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • V. A. Ponomarenko
    • 1
  • N. M. Khomutova
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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