Conclusions
-
1.
Binuclear complexes of rhodium in oxidation state I were obtained with bifunctional ligands: hexamethylenediamine, decamethylenediamine, 2,2′-diaminodiphenyl, o-phenanthroline, and 8,8′-dihydroxy-5,5′-diquinolyl.
-
2.
Mononuclear complexes of rhodium with 2,2′-diaminodiphenyl and o-phenanthroline were obtained.
-
3.
The formation of mononuclear complexes passes through the stage of binuclear complex formation, followed by rupture of the rhodium-nitrogen bond in the presence of excess ligand. It was proposed that one of the factors causing the formation of mononuclear complexes is the trans-effect of the carbonyl group.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
G. I. Karyakina and M. L. Khidekel', Izv. Akad. Nauk SSSR, Ser. Khim., 1916 (1969).
D. N. Lawson and Y. Wilkinson, J. Chem. Soc., 1900 (1965).
L. Vallarino, J. Chem. Soc., 2287 (1957).
R. Ugo, I. L. A. Monica, S. Cenini, and F. Bonati, J. Organometal. Chem.,11, 159 (1968).
T. A. Manuel, Advances Organometal. Chem.,3, 191 (1965).
I. A. McClevery and Y. W. Wilkinson, Inorgan. Synth.,8, 211 (1966).
I. P. Phillips, I. F. Deye, and T. Leach, Analyt. Chem. Acta,23, 131 (1960).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 940–942, April, 1970.
Rights and permissions
About this article
Cite this article
Karyakina, G.I., Khidekel', M.L. Carbonyl complexes of rhodium(I) with aliphatic and aromatic bifunctional ligands. Russ Chem Bull 19, 892–894 (1970). https://doi.org/10.1007/BF00867263
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00867263