Complex of bis(Dithioacetylacetonato)iron(II) with carbon monoxide, nitric oxide, and molecular oxygen

  • M. O. Broitman
  • Yu. G. Borodko
  • T. A. Stolyarova
  • A. E. Shilov
Brief Communications

Conclusions

  1. 1.

    bis(Dithioacetylacetonato)iron(II) is capable of complexing with carbon monoxide, nitric oxide, and oxygen. The complexes cis-Fe(C5H7S2)2(CO)2 and cis-Fe(C5H7S2)2(NO)2 are formed with CO and NO, respectively.

     
  2. 2.

    When CO reacts with Fe(C5H7S2)2 in the presence of pyridine, the monocarbonyl Fe(C5H7S2)2COPy is formed. If pyridine is replaced by m-phenylenediamine, a cyclic complex with bridging CO group is formed.

     

Keywords

Oxide Oxygen Iron Nitric Oxide Pyridine 

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Literature cited

  1. 1.
    A. San-Pjetro (editor), Nonheme Proteins: Role in Energy Conversion, Antioch Press, Ohio (1965), p. 261.Google Scholar
  2. 2.
    K. Knauer, P. Hemmerich, and I. D. W. van Woorst, Angew. Chem. Inter. Ed.,6, 262 (1967).Google Scholar
  3. 3.
    Analysis of Mineral Raw Materials [in Russian], Goskhimizdat (1950).Google Scholar
  4. 4.
    K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966).Google Scholar
  5. 5.
    A. Renovitch and W. A. Baker, J. Chem. Soc. A, 75 (1969).Google Scholar
  6. 6.
    M. S. Barvinok and I. S. Bukhareva, Zh. Neorgan. Khim.,10, 861 (1965).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • M. O. Broitman
    • 1
  • Yu. G. Borodko
    • 1
  • T. A. Stolyarova
    • 1
  • A. E. Shilov
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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