Complex of bis(Dithioacetylacetonato)iron(II) with carbon monoxide, nitric oxide, and molecular oxygen
- 20 Downloads
bis(Dithioacetylacetonato)iron(II) is capable of complexing with carbon monoxide, nitric oxide, and oxygen. The complexes cis-Fe(C5H7S2)2(CO)2 and cis-Fe(C5H7S2)2(NO)2 are formed with CO and NO, respectively.
When CO reacts with Fe(C5H7S2)2 in the presence of pyridine, the monocarbonyl Fe(C5H7S2)2COPy is formed. If pyridine is replaced by m-phenylenediamine, a cyclic complex with bridging CO group is formed.
KeywordsOxide Oxygen Iron Nitric Oxide Pyridine
Unable to display preview. Download preview PDF.
- 1.A. San-Pjetro (editor), Nonheme Proteins: Role in Energy Conversion, Antioch Press, Ohio (1965), p. 261.Google Scholar
- 2.K. Knauer, P. Hemmerich, and I. D. W. van Woorst, Angew. Chem. Inter. Ed.,6, 262 (1967).Google Scholar
- 3.Analysis of Mineral Raw Materials [in Russian], Goskhimizdat (1950).Google Scholar
- 4.K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966).Google Scholar
- 5.A. Renovitch and W. A. Baker, J. Chem. Soc. A, 75 (1969).Google Scholar
- 6.M. S. Barvinok and I. S. Bukhareva, Zh. Neorgan. Khim.,10, 861 (1965).Google Scholar