Advertisement

Syntheses based on lithium derivatives of p-carborane

  • L. I. Zakharkin
  • V. N. Kalinin
  • G. G. Zhigareva
Brief Communications
  • 47 Downloads

Conclusions

  1. 1.

    Starting from lithium-p-carboranes, the C-iodo-, mercapto-, benzoyl-, methylmercury-, ni-troso-, and amino-derivatives of p-carborane were obtained, p-Carboranesulfinic acid was also produced.

     
  2. 2.

    Iodine atoms in C-iodo-p-carborane have a “positive” character.

     
  3. 3.

    The reactivity of lithium-p-carborane is analogous to that of lithium-m-carborane.

     

Keywords

Lithium Iodine Benzoyl Methylmercury Iodine Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. I. Zakharkin, V. N. Kalinin, and L. S. Podvisotskaya, Inz. Akad. Nauk SSSR, Ser. Khim., 2661 (1968).Google Scholar
  2. 2.
    L. I. Zakharkin and L. S. Podvisotskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1464 (1965).Google Scholar
  3. 3.
    L. I. Zakharkin, V. N. Kalinin, and G. G. Zhigareva, Izv. Akad. Nauk SSSR, Ser. Khim., 2081 (1967).Google Scholar
  4. 4.
    L. I. Zakharkin, Dokl. Akad. Nauk SSSR,162, 818 (1965).Google Scholar
  5. 5.
    L. I. Zakharkin, A. I. L'vov, and L. S. Podvisotskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1905 (1965).Google Scholar
  6. 6.
    J. M. Kauffman, J. Grun, M. S. Cohen, and M. M. Iein, J. Amer. Chem. Soc.,86, 4210 (1964).Google Scholar
  7. 7.
    L. I. Zakharkin and V. N. Kalinin, Zh. Obshchei Khim.,35, 1882 (1965).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • V. N. Kalinin
    • 1
  • G. G. Zhigareva
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

Personalised recommendations