An unusual new reaction of α-olefins with magnesiumn-alkyl derivatives catalyzed by Cp2ZrCl2

  • U. M. Dzhemilev
  • O. S. Vostrikova
  • R. M. Sultanov
  • I. N. Batalina
Organic Chemistry Chemical Transformations Of Organic Compounds

Abstract

The reaction of organomagnesium compounds (OMC) containing alkyl radicals of normal structure with α-olefins, resulting in the formation of alkenylorganomagnesium compounds and accompanied by hydride transfer was discovered and systematically investigated. A scheme providing for the formation of zirconacyclopentane complexes was proposed for the mechanism of the reaction.

Keywords

synthesis catalysis α-olefins organomagnesium compounds zirconium complex mechanism zirconacyclopentanes 

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • U. M. Dzhemilev
  • O. S. Vostrikova
  • R. M. Sultanov
  • I. N. Batalina

There are no affiliations available

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