An unusual new reaction of α-olefins with magnesiumn-alkyl derivatives catalyzed by Cp2ZrCl2
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The reaction of organomagnesium compounds (OMC) containing alkyl radicals of normal structure with α-olefins, resulting in the formation of alkenylorganomagnesium compounds and accompanied by hydride transfer was discovered and systematically investigated. A scheme providing for the formation of zirconacyclopentane complexes was proposed for the mechanism of the reaction.
Keywordssynthesis catalysis α-olefins organomagnesium compounds zirconium complex mechanism zirconacyclopentanes
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