Dimer formation in the reaction of aryl halides catalyzed by nickel complexes

  • Yu. G. Budnikova
  • Yu. M. Kargin
  • V. V. Yanilkin
Brief Communications

Abstract

The synthesis of diaryls catalyzed by electrochemically generated zero-valent nickel with 2,2′-diapyridyl as the ligand was carried out from aryl halides in high yield. Feasibility was demonstrated for synthesizing the catalyst itself by the anodic dissolution of nickel in the presence of 2-bromopyridine in a diaphragmless cell.

Keywords

synthesis diaryls aryl halides 

References

  1. 1.
    J. K. Kochi,Organometallic Mechanisms and Catalysis, Academic Press, New York (1978).Google Scholar
  2. 2.
    P. W. Joley and G. Wille,The Organic Chemistry of Nickel, Vol. 1, Academic Press, New York (1974).Google Scholar
  3. 3.
    T. Kaufmann,Angew. Chem. 13, No. 7, 291 (1974).Google Scholar
  4. 4.
    F. Naso,Chim. Ind. (Milan) 61, 473 (1979).Google Scholar
  5. 5.
    G. Bontempelly and M. Fiorani,J. Electroanal. Chem. 160, Nos. 1–2, 249 (1984).Google Scholar
  6. 6.
    G. Bontempelly and M. Fiorani,Annali di Chimica 75, No. 1, 303 (1985).Google Scholar
  7. 7.
    G. Shiavon, G. Bontempelly, and B. Corain,J. Chem. Soc., Dalton Trans., No. 5, 1074 (1981).Google Scholar
  8. 8.
    C. Amatore and A. Jutand,Acta Chem. Scand. 44, No. 7, 755 (1990).Google Scholar

Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • Yu. G. Budnikova
  • Yu. M. Kargin
  • V. V. Yanilkin

There are no affiliations available

Personalised recommendations