Abstract
The qualitative and quantitative compositions of pyrazines that form in model glucose—ammonia and glucose—ammonia—leucine reactions in a glycerol medium were studied. Reaction conditions were found that ensure the synthesis of 23 alkylpyrazines in total concentration ∼6 g/kg. The obtained mixture of pyrazines is promising for use in the development of food aroma-forming substances.
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References
J. E. Hodge,J. Agric. Food Chem. 1, No. 5 928 (1953).
J. A. Maga and C. E. Sizer,J. Agric. Food Chem. 21, No. 1, 22 (1973).
J. A. Maga,Crit. Rev. Food Sci. Nutr. 14, 295 (1981).
J. C. Hoskin and P. S. Dimick,Process Biochem. 19, No. 14, 150 (1984).
T. Shibamoto and R. A. Bernhard,J. Agric. Food Chem. 24, No. 4, 847 (1976).
T. Shibamoto and R. A. Bernhard,J. Agric. Food Chem. 25, No. 3, 609 (1977).
T. Shibamoto and R. A. Bernhard,J. Agric. Food Chem. 26, No. 2, 183 (1978).
T. A. Misharina, R. V. Golovnya, V. N. Yakovleva, and S. V. Vitt,Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 1972 (1991).
S. T. Likens and G. B. Nickerson,Am. Soc. Brew. Chem. Proc., 5 (1964).
J. A. Newell, M. E. Mason, and R. S. Matlock,Food Chem. 15, 767 (1967).
G. P. Rizzi,J. Agric. Food Chem. 20, No. 6, 1081 (1972).
L. Kroh, S. Zeise, R. Stoser, and G. Westphal,Z. Lebensm. Unters. Forsch. 188, No. 2, 115 (1989).
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Institute of Food Substances, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 7, pp. 1628–1635, July, 1992.
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Misharina, T.A., Golovnya, R.V. & Yakovleva, V.N. Effect of time and temperature on the preparation of pyrazines in model reactions of the synthesis of aroma-forming substances. Russ Chem Bull 41, 1258–1263 (1992). https://doi.org/10.1007/BF00864192
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DOI: https://doi.org/10.1007/BF00864192