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Synthesis of the ethyl ester of the mononitrile of malonic acid by the catalytic carbonylation of benzenesulfonyloxyacetonitrile

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Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

A new method has been developed for the synthesis of the ethyl ester of the mononitrile of malonic acid by the carbonylation of benzenesulfonyloxyacetonitrile in absolute ethanol in the presence of cobalt carbonyl. The yield of the desired product was 30% with 60–90% conversion of the starting compound. The effects of temperature, pressure, and reaction time were studied.

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Literature cited

  1. B. A. Kazanskii (ed.), Organic Syntheses [Russian translation], Inos. Lit., Moscow (1949), p. 560.

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Authors
  1. A. L. Lapidus
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  2. S. D. Pirozhkov
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  3. A. R. Tumanova
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  4. T. G. Koksharova
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  5. N. V. Volkova
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  6. V. A. Bakulev
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  7. V. S. Mokrushin
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Additional information

N. D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 117913 Moscow. S. M. Kirov Urals Polytechnical Institute, Ekaterinburg. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 215–216, January, 1992.

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Lapidus, A.L., Pirozhkov, S.D., Tumanova, A.R. et al. Synthesis of the ethyl ester of the mononitrile of malonic acid by the catalytic carbonylation of benzenesulfonyloxyacetonitrile. Russ Chem Bull 41, 178–180 (1992). https://doi.org/10.1007/BF00863942

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  • DOI: https://doi.org/10.1007/BF00863942

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