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Metal complex-catalyzed synthesis of dihydrothiapyrans from dialkyl sulfoxides and 1,3-dienes

  • Organic Chemistry
  • Methods Of Synthesis
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

A preparative method has been developed for the synthesis of dihydrothiapyrans from dialkyl sulfoxides and 1,3-dienes, catalyzed by palladium and nickel complexes. The scope of this reaction has been assessed, and a mechanism proposed, using 1,3-dienes and sulfoxides of varying structure.

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Authors
  1. U. M. Dzhemilev
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  2. R. V. Kunakova
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  3. N. Z. Baibulatova
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  4. A. E. Tarasenko
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  5. É. M. Mustafina
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Additional information

Institute of Chemistry, Bashkir Science Center, Ural Branch, Russian Academy of Sciences, 450054 Ufa. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 160–166, January, 1992.

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Dzhemilev, U.M., Kunakova, R.V., Baibulatova, N.Z. et al. Metal complex-catalyzed synthesis of dihydrothiapyrans from dialkyl sulfoxides and 1,3-dienes. Russ Chem Bull 41, 128–134 (1992). https://doi.org/10.1007/BF00863928

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  • DOI: https://doi.org/10.1007/BF00863928

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