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Temperature dependence of sorptive deformation

  • Physical Chemistry
  • Adsorption. Heterogeneous Catalysis
  • Published:
Bulletin of the Russian Academy of Sciences, Division of chemical science Aims and scope

Abstract

A study has been made of the temperature dependence of deformation of CaA, CaX, and LaX zeolites when krypton or xenon is adsorbed, and also the deformation of activated carbon when dimethyl ether is adsorbed. It has been shown that the volume compressibility and the standard chemical potential of the adsorbate in a vacancy solution, within the interval of temperatures and pressures that were investigated, can be considered as linear functions of temperature. In this case, knowledge of the temperature dependence of sorptive deformation offers a means for calculating sorptive deformation curves for other temperatures.

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Literature cited

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Authors
  1. O. K. Krasil'nikova
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  2. M. E. Sarylova
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  3. L. A. Falko
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Additional information

Institute of Physical Chemistry, Russian Academy of Sciences, 117915 Moscow. Institute of Petrochemical Synthesis, Russian Academy of Sciences. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 1, pp. 23–28, January, 1992.

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Krasil'nikova, O.K., Sarylova, M.E. & Falko, L.A. Temperature dependence of sorptive deformation. Russ Chem Bull 41, 14–18 (1992). https://doi.org/10.1007/BF00863903

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  • DOI: https://doi.org/10.1007/BF00863903

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