Advertisement

Synthesis of aryl- and hetarylphosphonates

  • N. N. Demik
  • M. M. Kabachnik
  • Z. S. Novikova
  • I. P. Beletskaya
Organic Chemistry

Abstract

The reaction of tris(trimethylsilyl) phosphite with aryl or hetaryl halides under homogeneous catalysis conditions gave bis(trimethylsilyl)phosphonates. Treatment of these products with methanol gave the corresponding arylor hetarylphosphonic acids in quantitative yield.

Keywords

tris(trimethylsilyl) phosphite aryl and hetaryl halides homogeneous catalysis bis(trimethylsilyl)phosphonates arylphosphonic acids 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    P. Tavs,Chem. Ber.,103, 242 (1970).Google Scholar
  2. 2.
    I. V. Berdnik, V. V. Sentemov, and E. A. Krasil'nikova,Zh. Obshch. Khim.,56, No. 1, 223 (1986).Google Scholar
  3. 3.
    Ch. Yuan and H. Feng,Synthesis, No. 2, 140 (1990).Google Scholar
  4. 4.
    W. Boenigh and G. Hagete,Chem. Ber.,116, 2418 (1983).Google Scholar
  5. 5.
    I. Collins and S. M. Roberts,J. Chem. Soc., C, No. 1, 167 (1971).Google Scholar
  6. 6.
    S. M. Roberts,Chem. Commun., No. 17, 893 (1967).Google Scholar
  7. 7.
    A. Michaelis,Liebigs Ann. Chem.,18, 265 (1876).Google Scholar
  8. 8.
    A. Michaelis,Liebigs Ann. Chem.,193 (1896).Google Scholar

Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • N. N. Demik
  • M. M. Kabachnik
  • Z. S. Novikova
  • I. P. Beletskaya

There are no affiliations available

Personalised recommendations