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Gem-dinitro compounds in organic synthesis. 4. Use of the condensation product of glyoxal and dinitromethane in the synthesis of nitro-1,2,3-triazoles

  • A. T. Baryshnikov
  • V. I. Erashko
  • N. I. Zubanova
  • B. I. Ugrak
  • S. A. Shevelev
  • A. A. Fainzilberg
  • V. V. Semenov
Organic Chemistry

Abstract

The condensation of dinitromethane with glyoxal has been investigated and it has been demonstrated that 1,1,4,4-tetranitro-2,3-butandiol, α-hydroxy-β,β-dinitropropionic acid or their mixture may be formed. Interaction of 1,1,4,4-tetranitro-2,3-butandiol or 1,4-dibromo-1,1,4,4-tetranitro-2,3-butanediol diacetates with sodium azide leads to bis(5-nitro-1,2,3-triazol-4-yl) via intermediate 1,1,4,4-tetranitro-1,3-butadiene.

Keywords

gem-dinitroethylenes glyoxal dinitromethane dinitro compounds nitro-1,2,3-triazoles 1,1,4,4-tetranitro-2,3-butandiol α-hydroxy-β,β-dinitropropionic acid 

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Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • A. T. Baryshnikov
  • V. I. Erashko
  • N. I. Zubanova
  • B. I. Ugrak
  • S. A. Shevelev
  • A. A. Fainzilberg
  • V. V. Semenov

There are no affiliations available

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