Abstract
The relative rate constants of the addition of the C6H5CH2 radical to unsaturated compounds CH2=CHX (X = C4H9, SiMe3, CF3, CO2Me, CN) were determined under the conditions of initiation by the Fe(CO)5 + DMF system or by benzoyl peroxide. Depending on the values of the relative addition rate constants, the monomers can be arranged into the following series (X): CF3≈C4H9<SiMe3<CO2Me<CN. The relatively nucleophilic character of the benzyl radical has been shown. It was found that under the initiation conditions by the Fe(CO)5 + DMF system, the addition stage proceeds by a free radical mechanism.
Similar content being viewed by others
References
T. T. Vasil'eva, S. I. Gapusenko, C. V. Vitt, and A. B. Teretn'ev,Izv. Akad. Nauk, Ser. Khim., No. 2, 442 (1992).
R. Kh. Freidlina, F. K. Velichko, S. S. Zlotskii, D. L. Rakhmankulov, and A. B. Terent'ev,Radical Telomerization [in Russian], Khimiya, Moscow (1988), p. 17.
B. Giese, J. He, and W. Mehl,Chem. Ber. 121 No. 11, 2063 (1988).
R. G. Gasanov, T. T. Vasilieva, S. I. Gapusenko, and Y. A. Borisov,Mendeleev Commun., No. 3, 111 (1991).
T. T. Vasil'eva, L. F. Germanova, V. I. Dostovalova, B. V. Nelyubin, and R. Kh. Freidlina,Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 896 (1985).
A. B. Terent'ev, V. I. Dostovalova, and R. Kh. Freidlina,Org. Magn. Reson. 9, No. 6, 301 (1977).
Additional information
A. N. Nesmeyanov Institute of Heteroorganic Compounds, Russian Academy of Sciences, 117813 Moscow. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2017–2022, September, 1992.
Rights and permissions
About this article
Cite this article
Terent'ev, A.B., Gapusenko, S.I., Vasil'eva, T.T. et al. Relative kinetics of the radical addition of benzyl bromide to unsaturated compounds. Russ Chem Bull 41, 1567–1571 (1992). https://doi.org/10.1007/BF00863574
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00863574