Advertisement

Interaction of fluorine-containing 1,3-dicarbonyl compounds with polyamines

  • V. I. Saloutin
  • Z. É. Skryabina
  • Ya. V. Burgart
  • S. V. Kiseleva
Organic Chemistry
  • 30 Downloads

Abstract

In the reaction of fluorinated copper(II) 1,3-diketonates with diethylenetriamine (or triethylenetetramine) in CHCl3, N,N′-bis(1,3-aminovinylketones) are formed in 21–35% yields. Fluorine-containing 1,3-diketones and 1,3-ketoesters, upon interaction with polyamines without solvent, undergo acid cleavage, forming the corresponding amides. The copper(II) 1,3-ketoesterates are readily cleaved in CHCl3 at 25°C in excess triethylenetetramine or ethylenediamine.

Keywords

copper(II) 1,3-diketonates and 1,3-ketoesterates fluoroalkyl-containing 1,3-diketones and 1,3-ketoesters ethylenediamine diethylenetriamine triethylenetetramine N,N′-bis(1,3-aminovinylketones) acid cleavage 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    W. N. Wallis and S. C. Cummings,Inorg. Chem.,13, No. 4, 988 (1974).Google Scholar
  2. 2.
    S. C. Cummings and R. E. Sievers,Inorg. Chem.,11, No. 7, 1483 (1972).Google Scholar
  3. 3.
    S. C. Cummings and R. E. Sievers,J. Am. Chem. Soc.,92, No. 1, 215 (1970).Google Scholar
  4. 4.
    S. C. Cummings and R. E. Sievers,Inorg. Chem.,9, No. 5, 1131 (1970).Google Scholar
  5. 5.
    Z. É. Skryabina, Ya. V. Burgart, and V. I. Saloutin,Izv. Akad. Nauk SSSR, Ser. Khim., No. 4, 890 (1991).Google Scholar
  6. 6.
    Ya. V. Burgart, Z. É. Skryabina, and V. I. Saloutin,Izv. Akad. Nauk SSSR, Ser. Khim., No. 9, 2088 (1991).Google Scholar
  7. 7.
    D. H. Barton and W. D. Ollis,Comprehensive Organic Chemistry, Vol. 3, Sulphur, Selenium, Boron, and Organometallic Compounds, Pergamon Press, New York (1979).Google Scholar
  8. 8.
    I. L. Knunyants (ed.),Chemical Encyclopedia [in Russian], Vol. 2, Sov. Éntsikl., Moscow (1990).Google Scholar

Copyright information

© Plenum Publishing Corporation 1993

Authors and Affiliations

  • V. I. Saloutin
  • Z. É. Skryabina
  • Ya. V. Burgart
  • S. V. Kiseleva

There are no affiliations available

Personalised recommendations