Abstract
Water vapor, methanol, and argon adsorption isotherms, as well as the heat of adsorption of ammonia, methanol, and carbon dioxide have been determined on zeolite types A, ZK-4, and ZK-5. The results are explained by the distribution and the bond lengths of cations in the zeolite crystal lattice. It was shown that the exchange of 10–15% of the Na+ ions with Li+ in zeolite ZK-5 leads to a deformation of the 8-membered ring impeding the diffusion of adsorbed molecules. Cations contained in the 8-membered ZK-5 zeolite ring are bound more strongly to the framework, than in zeolite NaA, resulting in their smaller adsorption capacity.
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I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199164 St. Petersburg, Russia. Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2494–2500, November, 1992.
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Izmailova, S.G., Khvoshchev, S.S. & Shubaeva, M.A. Adsorption properties of low-silica zeolite ZK-5. Russ Chem Bull 41, 1960–1964 (1992). https://doi.org/10.1007/BF00863355
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DOI: https://doi.org/10.1007/BF00863355