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Measurement of the rate constants of the reaction of peroxy radicals with alcohols by the interlinked oxidation method with a selective inhibitor

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A method of interlinked oxidation of hydrocarbon with alcohol in the presence of a selective inhibitor is proposed for the measurement of the rate constant of the reaction of the peroxy radical with primary or secondary alcohols.

  2. 2.

    This method was used to measure the rate constants for the reaction of cyclohexenylperoxy radicals with benzyl alcohol, cyclohexanol, isopropyl alcohol, n-butanol, and ethanol at 60° and methanol at 40°.

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Literature cited

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    R. L. Vardanyan, E. T. Denisov & V. I. Zozulya

Authors
  1. R. L. Vardanyan
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  2. E. T. Denisov
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  3. V. I. Zozulya
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 611–613, March, 1972.

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Vardanyan, R.L., Denisov, E.T. & Zozulya, V.I. Measurement of the rate constants of the reaction of peroxy radicals with alcohols by the interlinked oxidation method with a selective inhibitor. Russ Chem Bull 21, 572–574 (1972). https://doi.org/10.1007/BF00863210

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  • DOI: https://doi.org/10.1007/BF00863210

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