Conclusions
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1.
A simple method is proposed for the study of the kinetics of fast reactions of atoms with molecules using an ESR spectrometer.
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2.
The theory of an integral diffusion method for the measurement of rate constants of elementary reactions was developed.
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3.
A preliminary measurement was made of the rate constant for the reaction O+NO2=NO+O2.
Literature cited
Yu. M. Gershenzon, A. B. Nalbandyan, and G. A. Sachyan, Dokl. Akad. Nauk SSSR,163, 927 (1965).
A. A. Westenberg, N. de Haas, and J. M. Rescoe, J. Phys. Chem.,74, 343 (1970).
M. Polanyi, Atomic Reactions, London (1932).
A. F. Dodonov, G. K. Lavrovskaya, V. P. Strunin, and V. L. Tal'roze, Kinetika i Kataliz,7, 385 (1966).
Yu. M. Gershenzon, Dokl. Akad. Nauk ArmSSR,34, 89 (1963).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimieheskay, No. 3, pp. 609–611, March, 1972.
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Gershenzon, Y.M., Dement'ev, A.P. & Moin, F.B. Integral diffusion method for the study of the kinetics of fast reactions in the resonator of an ESR spectrometer. Russ Chem Bull 21, 570–571 (1972). https://doi.org/10.1007/BF00863209
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DOI: https://doi.org/10.1007/BF00863209