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Effect of the nature of a phosphorus ligand on the character of the interaction of the central atom with the surrounding ligands in σ- arylcyclopentadienyliron carbonyl complexes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Fluorophenyl complexesπ-C6H5Fe(CO)(L)C6H4F-m, where L=CO, P(OC6H5)3, and P(C6H5)3 were synthesized.

  2. 2.

    The effect of phosphorus ligands on the interaction of the iron atom with the carbonyl andσ-aryl ligands was examined on the basis of IR and NMR spectra. In confirmation of the previously obtained data it is shown that the inductive effect predominates in the iron-aryl group interaction.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, L. G. Makarova & I. V. Polovyanyuk

Authors
  1. A. N. Nesmeyanov
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  2. L. G. Makarova
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  3. I. V. Polovyanyuk
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 607–609, March, 1972.

The authors thank V. B. Lokshin for obtaining the IR spectra.

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Nesmeyanov, A.N., Makarova, L.G. & Polovyanyuk, I.V. Effect of the nature of a phosphorus ligand on the character of the interaction of the central atom with the surrounding ligands in σ- arylcyclopentadienyliron carbonyl complexes. Russ Chem Bull 21, 567–569 (1972). https://doi.org/10.1007/BF00863208

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  • DOI: https://doi.org/10.1007/BF00863208

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