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Reaction of phosphorus ylids with perfluorobenzene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Triphenylphosphinemethylenes react with perfluorobenzene to form triphenylphosphinepentafluorophenylmethylenes.

  2. 2.

    Pentafluorostilbenes were obtained from triphenylphosphinepentafluorobenzylidene via the Wittig reaction.

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Literature cited

  1. J. M. Birchall and R. N. Haszeldine, J. Chem. Soc., 13 (1959).

  2. H. Staudinger and J. Meyer, Helv. Chim. Acta,2, 635 (1919).

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  3. R. Filler and E. Heffern, J. Organ. Chem.,32, No. 10, 3249 (1967).

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  4. V. P. Molosnova, V. I. Vysochin, V. A. Barkhash, and N. N. Vorozhtsov, Izv. Akad. Nauk SSSR, Ser. Khim., 146 (1969).

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Author information

Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    Nik A. Nesmeyanov, S. T. Berman & O. A. Reutov

Authors
  1. Nik A. Nesmeyanov
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  2. S. T. Berman
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  3. O. A. Reutov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 605–606, March, 1972.

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Nesmeyanov, N.A., Berman, S.T. & Reutov, O.A. Reaction of phosphorus ylids with perfluorobenzene. Russ Chem Bull 21, 564–566 (1972). https://doi.org/10.1007/BF00863207

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  • DOI: https://doi.org/10.1007/BF00863207

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