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Reaction of 2-methyl-3,5-heptadiyn-2-ol with glycols

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The reaction of 2-methyl-3,5-heptadiyn-2-ol withα-glycols in the presence of alkaline catalysts results in the formation of 1,3-dioxolanes, whileβ-glycols give ethynylvinyl ethers which contain a hydroxyl group in the alkoxy residue.

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Literature cited

  1. A. N. Volkov, Yu. M. Skvortsov, and Zh. A. Ovsepyan, Zh. Organ. Khim.,7, 653 (1971).

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  2. W. Chodkiewicz, Ann. Chimie (13),2, 819 (1957).

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  3. A. Sevin and W. Chodkiewicz, Tetrahedron Letters, 1953 (1965).

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, USSR

    A. N. Volkov, Yu. M. Skvortsov & Zh. A. Ovsepyan

Authors
  1. A. N. Volkov
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  2. Yu. M. Skvortsov
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  3. Zh. A. Ovsepyan
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 586–588, March, 1972.

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Volkov, A.N., Skvortsov, Y.M. & Ovsepyan, Z.A. Reaction of 2-methyl-3,5-heptadiyn-2-ol with glycols. Russ Chem Bull 21, 544–545 (1972). https://doi.org/10.1007/BF00863198

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  • DOI: https://doi.org/10.1007/BF00863198

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