Conclusions
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1.
σ-Benzyl-π-cyclopentadienyliron dicarbenyl is acylated in the benzene ring under the conditions of the Friedel-Crafts reaction.
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2.
The iron-carbon σ-bond in σ-benzyl-π-cyclopentadienyliron dicarbonyl was cleaved under the influence of halogens, mercuric bromide, and trifluoroacetic acid.
Literature cited
A. N. Nesmeyanov, T. B. Chenskaya, T. M. Babkhina, and I. I. Kritskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1187 (1970).
G. E. Coates, M. L. H. Green, and K. Wade, Organometallic Compounds, Third Edition, Vol. 2, London (1958), p. 233.
O. Smills and B. F. Hallam, J. Chem. Soc., 3030 (1956).
T. S. Piper and G. Wilkinson, J. Inorg. and Nucl. Chem.,2, 38 (1956).
R. B. King and R. N. Kapoor, J. Organometal. Chem.,15, 457 (1968).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 570–571, March, 1972.
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Nesmeyanov, A.N., Churanov, S.S., Guzman, I.S. et al. Reactions of σ-benzyl-π-cyclopentadienyliron dicarbonyl. Russ Chem Bull 21, 526–527 (1972). https://doi.org/10.1007/BF00863191
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DOI: https://doi.org/10.1007/BF00863191