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Reactions of σ-benzyl-π-cyclopentadienyliron dicarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    σ-Benzyl-π-cyclopentadienyliron dicarbenyl is acylated in the benzene ring under the conditions of the Friedel-Crafts reaction.

  2. 2.

    The iron-carbon σ-bond in σ-benzyl-π-cyclopentadienyliron dicarbonyl was cleaved under the influence of halogens, mercuric bromide, and trifluoroacetic acid.

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Literature cited

  1. A. N. Nesmeyanov, T. B. Chenskaya, T. M. Babkhina, and I. I. Kritskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 1187 (1970).

  2. G. E. Coates, M. L. H. Green, and K. Wade, Organometallic Compounds, Third Edition, Vol. 2, London (1958), p. 233.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 570–571, March, 1972.

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Nesmeyanov, A.N., Churanov, S.S., Guzman, I.S. et al. Reactions of σ-benzyl-π-cyclopentadienyliron dicarbonyl. Russ Chem Bull 21, 526–527 (1972). https://doi.org/10.1007/BF00863191

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  • DOI: https://doi.org/10.1007/BF00863191

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