Hydrogen bonding in some unsaturated alcohols

  • I. P. Povodyreva
  • R. R. Shagidullin
  • Z. G. Isaeva
Brief Communications
  • 22 Downloads

Conclusions

  1. 1.

    An intermolecular hydrogen bond between the hydroxyl group and the π-electrons of the six-membered ring in all of the unsaturated alcohols examined develops on pronounced dilution.

     
  2. 2.

    A conformational equilibrium exists for molecules of dl-α-terpineol with equatorial and axial isopropyl groups.

     

Keywords

Hydrogen Alcohol Hydroxyl Hydrogen Bond Isopropyl 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature cited

  1. 1.
    L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], Inostr. Lit. (1963), p. 137.Google Scholar
  2. 2.
    C. N. R. Rao, Chemical Applications of Infrared Spectroscopy, Academic Press, New York (1963), p. 178.Google Scholar
  3. 3.
    M. Tichi, Advances in Organic Chemistry [Russian translation], Vol. 5, Mir (1968), p. 157.Google Scholar
  4. 4.
    I. D. Campbell, G. Eglinton, and R. A. Raphael, J. Chem. Soc., B, 338 (1968).Google Scholar
  5. 5.
    M. Oki and H. Iwamura, Bull. Chem. Soc. Japan,35, 1552 (1962).Google Scholar
  6. 6.
    G. Eglinton, J. Martin, and W. Parker, J. Chem. Soc., 1243 (1965).Google Scholar
  7. 7.
    L. Joris, P. R. Schleyer, and R. Gleiter, J. Amer. Chem. Soc.,90, 327 (1968).Google Scholar
  8. 8.
    A. E. Lutskii, V. A. Granzhan, Ya. A. Shuster, and P. M. Zaitsev, Zh. Prikl. Spektr.,9, 913 (1969).Google Scholar
  9. 9.
    E. Eliel, N. Allinger, S. Angyal, and G. Morrison, Conformational Analysis [Russian translation], Mir (1969), p. 136.Google Scholar
  10. 10.
    H. D. Orloff, Chem. Rev.,54, 347 (1954).Google Scholar
  11. 11.
    Z. G. Isaeva, B. A. Arbuzov, V. V. Ratner, and I. P. Povodyreva, Izv. Akad. Nauk SSSR, Ser. Khim., 466 (1965).Google Scholar
  12. 12.
    Z. G. Isaeva, G. Sh. Bikbulatova, and B. A. Arbuzov, Dokl. Akad. Nauk SSSR,171, 107 (1966).Google Scholar

Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • I. P. Povodyreva
    • 1
    • 2
  • R. R. Shagidullin
    • 1
    • 2
  • Z. G. Isaeva
    • 1
    • 2
  1. 1.A. E. Arbuzov Institute of Organic and Physical ChemistryAcademy of Sciences of the USSRUSSR
  2. 2.Kazan Aviation InstituteUSSR

Personalised recommendations