Conclusions
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1.
The lower limit of spontaneous combustion in the raction of F2 with D2 depends on the rate of generation of active centers.
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2.
The expansion of the spontaneous combustion region for the reaction of F2 with D2 during external initiation confirms the previously stated nonlinear mechanism for branching.
Literature cited
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V. I. Vedeneev, V. I. Propoi, and O. M. Sarkisov, Kinetika i Kataliz,11, 36 (1970).
O. M. Sarkisov, Dissertation [in Russian], Moscow (1971).
V. I. Vedeneev, Yu. M. Gershenzon, A. P. Dement'ev, A. B. Nalbandyan, and O. M. Sarkisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1440 (1970).
Ya. B. Zel'dovich, Zh. Tekhn. Fiz.,11, No. 6, 493 (1941).
J. B. Anderson, J. Chem. Phys.,52, 3849 (1970).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 557–559, March, 1972.
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Bulatov, V.P., Vedeneev, V.I., Gershenzon, Y.M. et al. Nonlinear mechanism of spontaneous combustion in the reaction of fluorine with deuterium. Russ Chem Bull 21, 512–513 (1972). https://doi.org/10.1007/BF00863186
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DOI: https://doi.org/10.1007/BF00863186