Conclusions
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1.
The distribution coefficients of silver chloride, bromide, and iodide in sodium chloride, bromide, and iodide during the directed crystallization of ingots of different starting composition were determined.
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2.
A break which is apparently due to phase transitions in the sodium halides near the melting points is observed on the curves of the concentration dependence of the distribution coefficients of AgCl and AgBr when the silver halide concentration is 2.5%.
Literature cited
Handbook on the Fusion of Salt Systems [in Russian], Vol. 1, Izd. AN SSSR (1961).
V. I. Kosyakov, V. A. Isaenko, and A. N. Kirgintsev, Radiokhimiya,13, No. 4, 493 (1971).
A. N. Kirgintsev, V. A. Isaenko, and V. L. Kosyakov, Izv. Akad. Nauk SSSR, Ser. Khim., 444 (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 553–554, March, 1972.
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Kirgintsev, A.N., Kosyakov, V.I., Isaenko, V.A. et al. Distribution coefficients of silver halides during the directed crystallization of sodium halides. Russ Chem Bull 21, 507–508 (1972). https://doi.org/10.1007/BF00863184
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DOI: https://doi.org/10.1007/BF00863184