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Study of the association of fluorodinitromethane with aprotonic solvents by the PMR method

  • L. V. Okhlobystina
  • V. M. Khutoretskii
  • A. D. Naumov
  • A. V. Kessenikh
Brief Communications
  • 13 Downloads

Conclusions

  1. 1.

    The chemical shifts of the proton of fluorodinitromethane in a series of aprotonic solvents were studied at various concentrations of the solutions and temperatures.

     
  2. 2.

    Fluorodinitromethane forms complexes with many of the aprotonic solvents.

     
  3. 3.

    The chemical shift from the hydrogen bond of the proton of fluorodinitromethane can be used to evaluate the comparative basicities of solvents.

     

Keywords

Hydrogen Hydrogen Bond Chemical Shift Comparative Basicity Fluorodinitromethane 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    V. M. Khutoretskii, L. V. Okhlobystina, A. V. Kessenikh, and A. D. Naumov, Third All-Union Conference on the Chemistry of Nitro-Compounds, Summaries of Reports [in Russian], Nauka (1968), p. 79.Google Scholar
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Copyright information

© Consultants Bureau 1972

Authors and Affiliations

  • L. V. Okhlobystina
    • 1
  • V. M. Khutoretskii
    • 1
  • A. D. Naumov
    • 1
  • A. V. Kessenikh
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of Sciences of the USSRUSSR

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