Conclusions
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1.
The interaction of β-chloroethylvinyl ether in liquid ammonia medium with acetylides of acetals and alcoholates of acetylenic alcohols leads to the corresponding vinyl ether acetals and vinylacetylenic ethers of ethylene glycol.
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2.
The ethers obtained are readily hydrolyzed under the action of dilute hydrochloric acid.
Literature cited
V. M. Vlasov, G. G. Balezina, and É. I. Kositsyna, Zh. Organ. Khira.,2, 2137 (1966).
H. Kreimeier, US Patent No. 2106182, 1938; Chem. Abstracts,32, 2547 (1938).
M. F. Shostakovskii, V. M. Vlasov, and A. S. Dozhenitsyna, Izv. Akad. Nauk SSSR, Ser. Khim., 709 (1965).
O. Heuberger and L. N. Owen, J. Chem. Soc., 910 (1952).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 543–545, March, 1972.
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Balezina, G.G., Vlasov, V.M., Kolbina, S.E. et al. Some alkoxy-substituted vinyl ethers of the acetylene series. Russ Chem Bull 21, 496–498 (1972). https://doi.org/10.1007/BF00863180
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DOI: https://doi.org/10.1007/BF00863180