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Investigation of methylmercury derivatives of 1-phospha-7-, 1-phospha-12-, 1-arsa-7-, and 1-arsa-12-carbalkosododecaboranes(11) by the PMR method

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Methylmercury derivatives of m- and p-carbaphospha- and m- and p-carbaarsaboranes were synthesized.

  2. 2.

    The PMR spectra of the above-mentioned compounds were investigated, and it was established that the electron acceptor character of the systems increases in the series: p-HCB10H10CH ≤ p-AsB10H10CH<p-PB10H10CH and m-HCB10H10CH<m-AsB10H10CH<m-PB10H10CH.

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Literature cited

  1. L. I. Zakharkin and V. I. Kyskin, Izv. Akad. Nauk SSSR, Ser. Khim., 2806 (1970).

  2. L. I. Zakharkin and V. I. Kyskin, Izv. Akad. Nauk SSSR, Ser. Khim., 2053 (1971).

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    L. A. Fedorov, V. I. Kyskin & L. I. Zakharkin

Authors
  1. L. A. Fedorov
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  2. V. I. Kyskin
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  3. L. I. Zakharkin
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 536–538, March, 1972.

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Fedorov, L.A., Kyskin, V.I. & Zakharkin, L.I. Investigation of methylmercury derivatives of 1-phospha-7-, 1-phospha-12-, 1-arsa-7-, and 1-arsa-12-carbalkosododecaboranes(11) by the PMR method. Russ Chem Bull 21, 489–490 (1972). https://doi.org/10.1007/BF00863177

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  • DOI: https://doi.org/10.1007/BF00863177

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