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Silver acetylides in the reaction of ethynylation

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Triphenylethynyl derivatives of phosphorus, arsenic, and antimony were obtained by the interaction of silver phenylacetylide with PCl3, AsCl3, and SbCl3.

  2. 2.

    In the interaction of silver phenylacetylide and phenyldiacetylide with HgHal2 (Hal=Cl, Br, I), the corresponding ethynyl derivatives of mercury were obtained.

  3. 3.

    Bromination of silver phenylacetylide in ether yielded 1-bromo-2-phenylacetylene; the interaction of silver phenylacetylide with iodoform in dimethoxyethane leads to 1-iodo-2-phenylacetylene.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    I. R. Gol'ding & A. M. Sladkov

Authors
  1. I. R. Gol'ding
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  2. A. M. Sladkov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 529–530, March, 1972.

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Gol'ding, I.R., Sladkov, A.M. Silver acetylides in the reaction of ethynylation. Russ Chem Bull 21, 481–482 (1972). https://doi.org/10.1007/BF00863173

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  • DOI: https://doi.org/10.1007/BF00863173

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