Conclusions
-
1.
The IR spectra and the behavior of α-and γ-carboranyl-substituted acetoacetic esters in various solvents were discussed.
-
2.
The mutual conversion of the tautomeric form in the series of investigated compounds is substantially accelerated with increasing protophilic properties of the solvent.
This is a preview of subscription content, log in via an institution to check access.
Literature cited
L. I. Zakharkin, V. N. Kalinin, and I. P. Shepilov, Dokl. Akad. Nauk SSSR,174, 606 (1967).
L. I. Zakharkin, A. V. Grebennikov, and S. T. Ioffe, Izv. Akad. Nauk SSSR, Ser. Khim., 163 (1969).
L. I. Zakharkin and A. V. Grebennikov, Zh. Obshch. Khimii,34, 575 (1969).
O. Ya. Neiland and G. Ya. Vagan, Uspekhi Khimii,28, 436 (1959).
L. Bellamy, Infrared Spectra of Complex Molecules [Russian translation], IL (1963).
L. A. Leites, L. E. Vinogradova, V. N. Kalinin, and L. I. Zakharkin, Izv. Akad. Nauk SSSR, Ser. Khim., 1016 (1968).
S. T. Yoffe, I. E. Fedin, P. V. Petrovskii, and M. I. Kabachnik, Tetrahedron Letters, 2661 (1966).
Ch. Ingold, C. Shoppe, and J. Thorpe, J. Chem. Soc., 1477 (1926).
D. N. Shigorin, Izv. Akad. Nauk SSSR, Ser. Khim.,24, 596 (1953).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 521–524, March, 1972.
The author would like to thank L. I. Zakharkin and A. V. Grebennikov for kindly providing the compounds for the investigations.
Rights and permissions
About this article
Cite this article
Matrosov, E.I. IR spectra and behavior ofα- andγ-carboranyl-substituted acetoacetic esters in solutions. Russ Chem Bull 21, 473–475 (1972). https://doi.org/10.1007/BF00863170
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00863170