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The electronic effects of 1-[1,6-dicarbalkosodecaborane(10)]- and 1-[1,10-dicarbalkosodecaborane(10)]- groups

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The electronic influence of the 1-[1,6-dicarbalkosodecaborane(10)] (induction constant σi=0.10 and resonance constant σR 0=−0.02) and 1-[1,10-dicarbalkosodecaborane(10)] groups (σi=0.05 and σR 0=−0.02), which play the role of weak electron-acceptor groups, is manifested chiefly according to an inductive mechanism.

  2. 2.

    The nitration of 1-phenyl-1,10-dicarbalkosodecaborane(10) proceeds primarily in the p-position of the benzene ring.

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Literature cited

  1. F. N. Tebbe, P. M. Garrett, and M. F. Hawthorne, J. Amer. Chem. Soc.,90, 869 (1968).

    Google Scholar 

  2. Inorgan. Chem.,7, 1945 (1968).

  3. P. M. Garrett, J. C. Smart, and M. F. Hawthorne, J. Amer. Chem. Soc.,91, 4707 (1969).

    Google Scholar 

  4. R. W. Taft, E. Price, J. R. Fox, J. C. Lewis, K. K. Andersen, and G. T. Davis, J. Amer. Chem. Soc.,85, 709, 3146 (1963).

    Google Scholar 

  5. L. I. Zakharkin, V. N. Kalinin, A. P. Snyakin, and B. A. Kvasov, J. Organometal. Chem.,18, 19 (1969).

    Google Scholar 

  6. L. I. Zakharkin, V. N. Kalinin, E. G. Rys, and B. A. Kvasov, Izv. Akad. Nauk SSSR, Ser. Khim., 2570 (1971).

  7. L. I. Zakharkin, V. N. Kalinin, and L. S. Podvisotskaya, Izv. Akad. Nauk SSSR, Ser. Khim., 2661 (1968).

  8. L. I. Zakharkin and V. N. Kalinin, Dokl. Akad. Nauk SSSR,164, 577 (1965).

    Google Scholar 

  9. M. F. Hawthorne, T. E. Berry, and P. A. Wegner, J. Amer. Chem. Soc.,87, 4746 (1965).

    Google Scholar 

  10. P. M. Garrett, G. S. Ditta, and M. F. Hawthorne, Inorgan. Chem.,9, 1947 (1970).

    Google Scholar 

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 507–510, March, 1972.

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Zakharkin, L.I., Kalinin, V.N., Rys, E.G. et al. The electronic effects of 1-[1,6-dicarbalkosodecaborane(10)]- and 1-[1,10-dicarbalkosodecaborane(10)]- groups. Russ Chem Bull 21, 458–460 (1972). https://doi.org/10.1007/BF00863165

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  • DOI: https://doi.org/10.1007/BF00863165

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